The point is that encryption using PHP and MySQL can (and most likely do) differ. Even if they were both named, say MD5, it would be at best a fragile relationship if it ever worked to begin with.
Encryption is usually not a problem as it is not meant to be decrypted. So I question your need to do so. That said, if you want to encrypt with PHP use PHP to decrypt. If you are hoping to use PHP to decrypt what was encrypted in MySQL, phpMyAdmin or otherwise, I’m afraid you’re out of luck.