Trust us. What you're doing will lead you to madness.
First off, Word is a terrible way to generate anything Web-related. I kid you not, I took Word off my computer at home entirely, and write everything either in text documents or in HTML/CSS.
Microsoft thinks Word can generate Web pages, and it can: horrible, awful pages that look terrible and don't work well in a browser. Microsoft also thinks it makes a good browser in Internet Explorer. It didn't. Go with Firefox instead, or Opera or Chrome or Safari or anything except IE. And stop using Word entirely except to generate Word documents. Seriously.
If you want to whip out a quick and dirty Web site without bothering to learn HTML and CSS, you can do it by using a free page generator like Mozilla's Seamonkey, Kompozer, or something similar. They won't be particularly good, but they will be a lot better than anything MS Word will generate.
If you want to learn to do it the right way, there are a lot of good tutorial sites out there that will get you started. You can also learn by buying books like Sitepoint's Build Your Own Web Site or the HeadFirst series. And you can post your questions in these forums. The only program you will need is Notepad, and you have that in Accessories.
I'd quit designing Web sites and take up crocheting before I'd do it the way you're trying to do it.