Ensure that the mail the your server sends is RFC compliant. This ensures that mail servers that penalize messages sent in a non-compliant standard are more likely to pass mail from your server.
Ensure that your firewall does antivirus/malware/spyware both in and out.
Ensure that you check RBL services and ensure you're not being blocked by anyone. If you are, then it gives you a point to understand why you're blocked.
Ensure you dns and reverse dns are from the same location. Many servers bock at reverse DNS records being different then the senders domain address.
Ensure your not on a shared server where the IP of the machine or (ip block) of the virtual servers aren't blocked in bulk so not only the offenders you the people playing nicely are banded from people's servers.
One thing to also know if are your emails arriving in other peoples junk folder or being blocked before they get there?