It may sound a basic question, but having just started with the jump start Responsive design book, everything is aligned left, how do you get it to align in the centre I have tried with no success so far
Welcome to the forums, @prh108. 
As with many things in CSS, it depends what you want to centre, and what other elements you have in the design, but for many purposes, using margin: 0 auto; will do the trick.
There is a useful article here, covering various techniques:
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