what you forgot to mention is the foreign key, tsk tsk 
however, having seen a few of your previous threads, i'm gonna guess that it's a composite key, and from the first query you posted, i'm gonna guess that it's a 3-column composite key
Code:
SELECT m.business_id
, m.content_category
, m.menu_name
FROM menus as m
LEFT OUTER
JOIN menus_sequencer as ms
ON ms.business_id = m.business_id
AND ms.content_category = m.content_category
AND ms.menu_name = m.menu_name
WHERE ms.business_id IS NULL
the part in red is where the query attempts to make the correct join
the part in blue is where you detect that the join didn't find a matching row
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