There are not many resources dedicated to Photo-Paint. This is unfortunate because Corel offers such a powerful suite of applications.
However, http://www.designer.com (corel's own resource site) does have a wealth of information including tutorials and links to other sites. You may find something there.
Also keep in mind that, with a little "translation", many photoshop tutorials are very useful for learning Photo-Paint, as both programs share similiar features and filters.
Hope this helps.
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