Just a little article about Ruby, not RoR:
http://www.joelonsoftware.com/items/2006/09/12.html
Take a look at what David Heinemeier Hansson, the author of RoR, had to say.
From my side you clearly want a framework so there are two things I would recommend you for sure. Try all of the frameworks that appeal you (check things like pre-production environment setup, production environment setup, deployment cycle...) and make a little survey, see whether or not you have the possibilities (hosting and customers) for developing in that framework, because you seem a pragmatic person.
And don't forget, you may probably not leverage the framework enough if you don't know the language enough as well as some paradigms of programming. Pay attention to communities (I don't think there is a problem right here with whether RoR, PHP or Django), libraries and tools that could make your life easier, like editors.
P.S: Just for fun:
http://www.youtube.com/watch?v=n1NVfDlU6yQ
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