I'm not sure if it is apossible with Dreamweaver, but don't forget that XML is only read by XML compatible browsers and that means IE5 at the moment. If you are sure your user are using IE5 then you can use what MS term as an XML data island e.g.
<BLOCKQUOTE><font size="1" face="Verdana, Arial">code/font><HR><pre>
<XML id="yourid">
<XMLTAG>
<ANOTHERTAG/>
</XMLTAG>
</XML>
[/code]
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