I started all those years ago, right here on Sitepoint by reading Kev Yank's "Build your own Database Driven Website using PHP & MySQL" tutorial.
The series has been kept up to date and is now in it's third revision. It's a great starting point, walking you through the steps for setting up a simple CMS. For me this worked great as a starting point because it allowed me to see the code come to life, walking me through the steps needed to actually make something that works rather than just reading reams of code about the more complex aspects of PHP that might scare a beginner off.
This series helped get me bit by the PHP bug and I'd reccommend it highly. The url is
http://www.sitepoint.com/article/php-mysql-tutorial
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